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Subsequently, the second [2,3]-sigmatropic rearrangement of INT2-S yields the para -amination intermediate INT3-S via TS2-S (with a barrier of 5.0 kcal mol 1 , see path 1-S )

doi: 10.2460/javma.236.8.880

The research was supported in part by the National Institute of Dental and Craniofacial Research (R01DE025037 and R01DE027374).

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