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Reactive oxygen species are created as a byproduct of hemolysis via processes involving free hemoglobin

This is why a peptide-only approach without addressing these foundational factors often produces underwhelming results

10.1007/s11910-012-0325-0 35 FranksN

The high activity of 30 prompted a synthesis of the corresponding disulfide 32 with a 14-membered ring system anticipated be able to adopt a similar trans conformation as 30