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Owing to multiple hydrogen bonds formed by the urethane group, IU, and TA in the hydrogel network, the PTK hydrogel showed a high fracture strength of 1.1 MPa, stable mechanical properties during 28000 tensile cycles, and promising shape memory capability, which made it suitable for minimally invasive surgery and maintained the network integrity during constant mechanical stimulation in joint movement

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Endogenous glutathione adducts