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This design choice was dictated by the requirement that the amine functionality remain accessible to ensure intracellular biological activity, despite the presence of additional functional groups within the drug scaffold 40,41,42

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The balance between reactive oxygen species (ROS) and antioxidants plays a crucial role in cancer chemoresistance, influencing drug efflux, epithelial-to-Mesenchymal Transition (EMT), pro-survival signalling, and apoptosis inhibition [76, 77]